X-ray synchrotron study of liquid-vapor interfaces at short length scales: effect of long-range forces and bending energies.

نویسندگان

  • S Mora
  • J Daillant
  • K Mecke
  • D Luzet
  • A Braslau
  • M Alba
  • B Struth
چکیده

We have investigated the small-scale structure of the liquid-vapor interface using synchrotron x-ray scattering for liquids with different molecular structures and interactions. The effective momentum-dependent surface energy first decreases from its macroscopic value due to the effect of long-range forces, and then increases with increasing wave vector. The results are analyzed using a recent density functional theory. The large wave-vector increase is attributed to a bending energy for which local and nonlocal contributions are equally important.

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عنوان ژورنال:
  • Physical review letters

دوره 90 21  شماره 

صفحات  -

تاریخ انتشار 2003